Effect of Sun Light on Plastic Water Container Made from Polyethylene Terephthalate
Abstract
Polyethylene terephthalate (PET) is commonly used in water bottle manufacturing because of its low cost, transparency, lightweight nature, and durability. However, PET can degrade when exposed to sunlight and high temperatures for long periods. This study developed a predictive model to evaluate photodegradation behavior of PET water bottles under different sunlight conditions. The investigation focused on thermal degradation kinetics, UV absorbance changes, and chemical migration through diffusion. Results showed that higher UV intensity and temperature accelerated PET degradation, leading to discoloration and increased migration of compounds such as antimony. Under extreme sunlight exposure, antimony levels approached critical safety limits within a short time. Survival analysis further indicated that the lifespan of PET bottles decreased significantly, from several hundred hours under normal conditions to less than two days under severe exposure. Predictive model showed good agreement with previously reported studies and provides useful insight about durability, stability, and safety of PET packaging materials under environmental stress conditions.
References
- Abdel Hakim, A. E., & Sultan, M. (2023). Migration of acetaldehyde and formaldehyde from PET-bottled water under hot climate conditions. Egyptian Journal of Chemistry, 66(11), 573–583.
- Al-Azzawi, F. (2015). Degradation studies on recycled polyethylene terephthalate (Doctoral dissertation, London Metropolitan University).
- Alqahtani, S., Alqahtani, S., Saquib, Q., & Mohiddin, F. (2023). Toxicological impact of microplastics and nanoplastics on humans: Understanding the mechanistic aspect of the interaction. Frontiers in Toxicology, 5, 1193386.
- Al-Saleh, I., Shinwari, N., & Alsabbaheen, A. (2011). Phthalates residues in plastic bottled waters. The Journal of Toxicological Sciences, 36(4), 469–478.
- Auguste, M., Lasa, A., Balbi, T., Pallavicini, A., Vezzulli, L., & Canesi, L. (2020). Impact of nanoplastics on hemolymph immune parameters and microbiota composition in Mytilus galloprovincialis. Marine Environmental Research, 159, 105017.
- Bach, C., Dauchy, X., Chagnon, M. C., & Etienne, S. (2012). Chemical compounds and toxicological assessments of drinking water stored in polyethylene terephthalate (PET) bottles: A source of controversy reviewed. Water Research, 46(3), 571–583.
- Baeza-Martínez, C., Olmos, S., González-Pleiter, M., López-Castellanos, J., García-Pachón, E., Masiá-Canuto, M., ... & Bayo, J. (2022). First evidence of microplastics isolated in European citizens’ lower airway. Journal of Hazardous Materials, 438, 129439.
- Cao, G., & Cai, Z. (2023). Getting health hazards of inhaled nano/microplastics into focus: Expectations and challenges. Environmental Science & Technology, 57(9), 3461–3463.
- Chaisupakitsin, M., Chairat-Utai, P., & Jarusiripot, C. (2019). Degradation of polyethylene terephthalate bottles after long sunlight exposure. Songklanakarin Journal of Science & Technology, 41(2).
- Cormack, P. A., Erdemli, O. C., & Sankey, S. W. (2021). Polymerizable UV absorbers for the UV stabilization of polyesters. II. Photodegradation study of UV-stabilized PET copolymers. Arkivoc, 315–330.
- Danso, I. K., Woo, J. H., & Lee, K. (2022). Pulmonary toxicity of polystyrene, polypropylene, and polyvinyl chloride microplastics in mice. Molecules, 27(22), 7926.
- EFSA Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF). (2011). Scientific opinion on the criteria to be used for safety evaluation of a mechanical recycling process to produce recycled PET intended to be used for manufacture of materials and articles in contact with food. EFSA Journal, 9(7), 2184.
- Huang, S., Huang, X., Bi, R., Guo, Q., Yu, X., Zeng, Q., ... & Guo, P. (2022). Detection and analysis of microplastics in human sputum. Environmental Science & Technology, 56(4), 2476–2486.
- Jenner, L. C., Rotchell, J. M., Bennett, R. T., Cowen, M., Tentzeris, V., & Sadofsky, L. R. (2022). Detection of microplastics in human lung tissue using μFTIR spectroscopy. Science of the Total Environment, 831, 154907.
- Kelly, F. J., & Fussell, J. C. (2020). Toxicity of airborne particles—Established evidence, knowledge gaps and emerging areas of importance. Philosophical Transactions of the Royal Society A, 378(2183).
- Lee, A. G., Kang, S., Yoon, H. J., Im, S., Oh, S. J., & Pak, Y. K. (2023). Polystyrene microplastics exacerbate systemic inflammation in high-fat diet-induced obesity. International Journal of Molecular Sciences, 24(15), 12421.
- Li, X., Zhang, T., Lv, W., Wang, H., Chen, H., Xu, Q., ... & Dai, J. (2022). Intratracheal administration of polystyrene microplastics induces pulmonary fibrosis by activating oxidative stress and Wnt/β-catenin signaling pathway in mice. Ecotoxicology and Environmental Safety, 232, 113238.
- Liao, Z., Ji, X., Ma, Y., Lv, B., Huang, W., Zhu, X., ... & Shang, X. (2021). Airborne microplastics in indoor and outdoor environments of a coastal city in Eastern China. Journal of Hazardous Materials, 417, 126007.
- Lim, D., Jeong, J., Song, K. S., Sung, J. H., Oh, S. M., & Choi, J. (2021). Inhalation toxicity of polystyrene micro (nano) plastics using modified OECD TG 412. Chemosphere, 262, 128330.
- Liu, P., Shao, L., Li, Y., Jones, T., Cao, Y., Yang, C. X., ... & BéruBé, K. (2022). Microplastic atmospheric dustfall pollution in urban environment: Evidence from the types, distribution, and probable sources in Beijing, China. Science of The Total Environment, 838, 155989.
- Liu, S., Li, H., Wang, J., Wu, B., & Guo, X. (2022). Polystyrene microplastics aggravate inflammatory damage in mice with intestinal immune imbalance. Science of The Total Environment, 833, 155198.
- Park, I., Yang, W., & Lim, D. K. (2022). Current status of organic matters in bottled drinking water in Korea. ACS ES&T Water, 2(5), 738–748.
- Prater, R. L., Manjeshwar, P. R., Franckhauser, A. W., Durham, D. J., Stenmark, N. G., & McGrath, D. S. (2020). Study of UV degradation on plastic (PET) aerosols. Journal of Applied Packaging Research, 12(1), 8.
- Shotyk, W., Krachler, M., & Chen, B. (2006). Contamination of Canadian and European bottled waters with antimony from PET containers. Journal of Environmental Monitoring, 8(2), 288–292.
- Welle, F., & Franz, R. (2011). Migration of antimony from PET bottles into beverages: Determination of the activation energy of diffusion and migration modelling compared with literature data. Food Additives & Contaminants: Part A, 28(1), 115–126.
- Yang, S., Zhang, T., Ge, Y., Yin, L., Pu, Y., & Liang, G. (2024). Inhalation exposure to polystyrene nanoplastics induces chronic obstructive pulmonary disease-like lung injury in mice through multi-dimensional assessment. Environmental Pollution, 347, 123633.
- Zhu, X., Huang, W., Fang, M., Liao, Z., Wang, Y., Xu, L., ... & Shang, X. (2021). Airborne microplastic concentrations in five megacities of northern and southeast China. Environmental Science & Technology, 55(19), 12871–12881.
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